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Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO2 conversion

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Abstract

A mesoporous imine-functionalized organic polymer (Imine-POP) was prepared based on the reaction of an aryl ammonium salt with an aromatic aldehyde in water without any catalyst and template. The Pd coordinated Imine-POP exhibited high catalytic activity for the N-formylation of amines with CO2/H2 at 100 °C, affording a series of formamides in high yields.

Graphical abstract: Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO2 conversion

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Publication details

The article was received on 25 Apr 2018, accepted on 12 Jun 2018 and first published on 13 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03346C
Citation: Chem. Commun., 2018, Advance Article
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    Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO2 conversion

    X. Yu, Z. Yang, S. Guo, Z. Liu, H. Zhang, B. Yu, Y. Zhao and Z. Liu, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC03346C

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