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Issue 49, 2018
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Cp*Ir(III)-catalyzed C–H/N–H functionalization of sulfoximines for the synthesis of 1,2-benzothiazines at room temperature

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Abstract

The first Cp*Ir(III)-catalyzed C–H/N–H bond functionalization of sulfoximines with α-diazocarbonyl compounds has been developed for the synthesis of 1,2-benzothiazines under redox-neutral conditions. The reactions proceed at room temperature with excellent functional group tolerance and high yields without the requirement of any silver additive.

Graphical abstract: Cp*Ir(iii)-catalyzed C–H/N–H functionalization of sulfoximines for the synthesis of 1,2-benzothiazines at room temperature

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Publication details

The article was received on 23 Apr 2018, accepted on 23 May 2018 and first published on 23 May 2018


Article type: Communication
DOI: 10.1039/C8CC03288B
Citation: Chem. Commun., 2018,54, 6288-6291
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    Cp*Ir(III)-catalyzed C–H/N–H functionalization of sulfoximines for the synthesis of 1,2-benzothiazines at room temperature

    Y. N. Aher, D. M. Lade and A. B. Pawar, Chem. Commun., 2018, 54, 6288
    DOI: 10.1039/C8CC03288B

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