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Issue 57, 2018
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Visible-light induced three-component alkynyl-difluoroalkylation of unactivated alkenes

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Abstract

A visible-light induced three-component reaction of difluoroalkyl halides, unactivated alkenes, and alkynyl sulfones is described, providing a direct and general approach to the construction of synthetically valuable β-difluoroalkylated alkynes under room temperature conditions. This represents the first intermolecular alkynyl-difluoroalkylation of unactivated alkenes.

Graphical abstract: Visible-light induced three-component alkynyl-difluoroalkylation of unactivated alkenes

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Publication details

The article was received on 18 Apr 2018, accepted on 21 Jun 2018 and first published on 22 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03105C
Citation: Chem. Commun., 2018,54, 7924-7927
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    Visible-light induced three-component alkynyl-difluoroalkylation of unactivated alkenes

    W. Jin, M. Wu, Z. Xiong and G. Zhu, Chem. Commun., 2018, 54, 7924
    DOI: 10.1039/C8CC03105C

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