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Issue 49, 2018
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The first lead fluorooxoborate PbB5O8F: achieving the coexistence of large birefringence and deep-ultraviolet cut-off edge

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Abstract

Herein, the first lead fluorooxoborate PbB5O8F has been structurally designed following a strategy of fluorine introduction into borates. PbB5O8F presents the first case of possessing the [B5O10F]6− fundamental building block. More importantly, PbB5O8F fully achieves the coexistence of large birefringence and deep-ultraviolet cut-off edge. This short cut-off edge sets a new record among lead borates.

Graphical abstract: The first lead fluorooxoborate PbB5O8F: achieving the coexistence of large birefringence and deep-ultraviolet cut-off edge

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Publication details

The article was received on 04 Apr 2018, accepted on 21 May 2018 and first published on 21 May 2018


Article type: Communication
DOI: 10.1039/C8CC02694G
Citation: Chem. Commun., 2018,54, 6308-6311
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    The first lead fluorooxoborate PbB5O8F: achieving the coexistence of large birefringence and deep-ultraviolet cut-off edge

    M. Mutailipu, M. Zhang, B. Zhang, Z. Yang and S. Pan, Chem. Commun., 2018, 54, 6308
    DOI: 10.1039/C8CC02694G

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