Exploiting 13C/14N solid-state NMR distance measurements to assign dihedral angles and locate neighboring molecules

Giovanna M. Pope; Ivan Hung; Zhehong Gan; Hani Mobarak; Göran Widmalm; James K. Harper

doi:10.1039/C8CC02597E

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Exploiting ¹³C/¹⁴N solid-state NMR distance measurements to assign dihedral angles and locate neighboring molecules†

Giovanna M. Pope,^a Ivan Hung,^b Zhehong Gan,^b Hani Mobarak,^c Göran Widmalm

^c and James K. Harper

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Central Florida, 4111 Libra Dr., Orlando, FL 32816, USA
E-mail: james.harper@ucf.edu

^b National High Magnetic Field Laboratory, 1800 E. Paul Dirac Dr., Tallahassee, FL 32310, USA

^c Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91 Stockholm, Sweden

Abstract

The RESPDOR NMR method rapidly provides multiple ¹³C/¹⁴N distance measurements in natural abundance solids. In this study, ¹³C/¹⁴N RESPDOR information is shown, for the first time, to provide accurate molecular conformation and to locate non-bonded neighboring molecules.

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Article information

DOI: https://doi.org/10.1039/C8CC02597E
Article type: Communication
Submitted: 30 Mar 2018
Accepted: 31 May 2018
First published: 31 May 2018

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Chem. Commun., 2018,54, 6376-6379

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Exploiting ¹³C/¹⁴N solid-state NMR distance measurements to assign dihedral angles and locate neighboring molecules

G. M. Pope, I. Hung, Z. Gan, H. Mobarak, G. Widmalm and J. K. Harper, Chem. Commun., 2018, 54, 6376 DOI: 10.1039/C8CC02597E

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