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A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

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Abstract

We report a new lead-free perovskite-like hybrid, composed of hexamethyleneimine and one-dimensional [SbCl5]n2− polyanionic zigzag chains, which shows above-room-temperature switching of quadratic nonlinear optical (NLO) properties induced by the unique order–disorder conformational changes of the organic cation.

Graphical abstract: A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

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Publication details

The article was received on 28 Mar 2018, accepted on 17 Apr 2018 and first published on 18 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC02496K
Citation: Chem. Commun., 2018, Advance Article
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    A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

    J. Zhang, S. Han, X. Liu, Z. Wu, C. Ji, Z. Sun and J. Luo, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC02496K

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