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Formal water oxidation turnover frequencies from MIL-101(Cr) supported Ru(bda) depend on oxidant concentration

Abstract

THE MOLECULAR WATER OXIDATION CATALYST [RU(BDA)(L)2] HAS BEEN INCORPORATED INTO PYRIDINE-DECORATED MIL-101(CR) METAL ORGANIC FRAMEWORKS. THE RESULTING MIL-101@RU MATERIALS EXHIBIT TURNOVER FREQUENCIES (TOFS) UP TO TEN TIMES HIGHER COMPARED TO THE HOMOGENOUS REFERENCE. AN UNUSUAL DEPENDENCE OF THE FORMAL TOFS ON OXIDANT CONCENTRATION IS OBSERVED THAT ULTIMATELY ARISES FROM DIFFERING AMOUNTS OF CATALYSTS IN THE MOF CRYSTALS BEING ACTIVE.

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Publication details

The article was received on 24 Mar 2018, accepted on 12 Jun 2018 and first published on 12 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC02300J
Citation: Chem. Commun., 2018, Accepted Manuscript
  • Open access: Creative Commons BY license
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    Formal water oxidation turnover frequencies from MIL-101(Cr) supported Ru(bda) depend on oxidant concentration

    A. Bhunia, B. Johnson, J. Czapla-Masztafiak, J. Sa and S. Ott, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC02300J

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