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Issue 40, 2018
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Chemoselective epoxidation of cholesterol derivatives on a surface-designed molecularly imprinted Ru–porphyrin catalyst

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Abstract

A new molecularly imprinted Ru–porphyrin complex catalyst on a SiO2 support was designed, prepared, and characterized in a step-by-step manner for the C5[double bond, length as m-dash]C6 epoxidation of cholesterol derivatives. High chemoselectivity for the C5[double bond, length as m-dash]C6 epoxidation of cholesterol derivatives without protecting the 3-position OH group and other oxidizable functional groups was achieved on the molecularly imprinted catalyst.

Graphical abstract: Chemoselective epoxidation of cholesterol derivatives on a surface-designed molecularly imprinted Ru–porphyrin catalyst

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Publication details

The article was received on 01 Feb 2018, accepted on 20 Apr 2018 and first published on 02 May 2018


Article type: Communication
DOI: 10.1039/C8CC00896E
Citation: Chem. Commun., 2018,54, 5114-5117
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    Chemoselective epoxidation of cholesterol derivatives on a surface-designed molecularly imprinted Ru–porphyrin catalyst

    S. Muratsugu, H. Baba, T. Tanimoto, K. Sawaguchi, S. Ikemoto, M. Tasaki, Y. Terao and M. Tada, Chem. Commun., 2018, 54, 5114
    DOI: 10.1039/C8CC00896E

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