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Issue 38, 2018
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Tuning the structure and catalytic activity of Ru nanoparticle catalysts by single 3d transition-metal atoms in Ru12–metalloporphyrin precursors

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Abstract

Ru nanoparticle catalysts were prepared from Ru12–metalloporphyrin complex precursors containing 3d transition-metal atoms attached to SiO2 surfaces. The single 3d metal atoms at the central position of the Ru12–metalloporphyrin complex precursors exerted a significant influence on the structures and hydrogenation performance of the Ru nanoparticles on the SiO2 surfaces. The Ru12–Cu–porphyrin complex afforded positively charged Ru nanoparticles, which would provide high activity toward aromatic hydrogenation.

Graphical abstract: Tuning the structure and catalytic activity of Ru nanoparticle catalysts by single 3d transition-metal atoms in Ru12–metalloporphyrin precursors

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Publication details

The article was received on 26 Dec 2017, accepted on 18 Apr 2018 and first published on 26 Apr 2018


Article type: Communication
DOI: 10.1039/C7CC09862F
Citation: Chem. Commun., 2018,54, 4842-4845
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    Tuning the structure and catalytic activity of Ru nanoparticle catalysts by single 3d transition-metal atoms in Ru12–metalloporphyrin precursors

    S. Muratsugu, A. Yamaguchi, G. Yokota, T. Maeno and M. Tada, Chem. Commun., 2018, 54, 4842
    DOI: 10.1039/C7CC09862F

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