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Issue 23, 2017
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Infrared electrochromic conducting polymer devices

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Abstract

The conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) is well known for its electrochromic properties in the visible region. Less focus has been devoted to the infrared (IR) wavelength range, although tunable IR properties could enable a wide range of novel applications. As an example, modern day vehicles have thermal cameras to identify pedestrians and animals in total darkness, but road and speed signs cannot be easily visualized by these imaging systems. IR electrochromism could enable a new generation of dynamic road signs that are compatible with thermal imaging, while simultaneously providing contrast also in the visible region. Here, we present the first metal-free flexible IR electrochromic devices, based on PEDOT:Tosylate as both the electrochromic material and electrodes. Lateral electrochromic devices enabled a detailed investigation of the IR electrochromism of thin PEDOT:Tosylate films, revealing large changes in their thermal signature, with effective temperature changes up to 10 °C between the oxidized (1.5 V) and reduced (−1.5 V) states of the polymer. Larger scale (7 × 7 cm) vertical electrochromic devices demonstrate practical suitability and showed effective temperature changes of approximately 7 °C, with good optical memory and fast switching (1.9 s from the oxidized state to the reduced state and 3.3 s for the reversed switching). The results are highly encouraging for using PEDOT:Tosylate for IR electrochromic applications.

Graphical abstract: Infrared electrochromic conducting polymer devices

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Publication details

The article was received on 16 Jan 2017, accepted on 08 May 2017 and first published on 30 May 2017


Article type: Paper
DOI: 10.1039/C7TC00257B
Citation: J. Mater. Chem. C, 2017,5, 5824-5830
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    Infrared electrochromic conducting polymer devices

    R. Brooke, E. Mitraka, S. Sardar, M. Sandberg, A. Sawatdee, M. Berggren, X. Crispin and M. P. Jonsson, J. Mater. Chem. C, 2017, 5, 5824
    DOI: 10.1039/C7TC00257B

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