Trivalent cerium-preponderant CeO2/graphene sandwich-structured nanocomposite with greatly enhanced catalytic activity for the oxygen reduction reaction

Abstract

A sandwich-like CeO₂/graphene nanocomposite (CeGS) with a uniform thin CeO₂ crystalline film coating on reduced graphene oxide is presented. Large amounts of trivalent Ce and abundant oxygen vacancies (V_O) were introduced onto the surface of CeGS. Due to the advantageous surficial crystal configuration, this CeGS displayed greatly enhanced catalytic activity and excellent durability for the oxygen reduction reaction (ORR). By DFT calculations, it was demonstrated that the Ce(III)-preponderant and V_O-containing surface benefited the intense chemical adsorption and activation of O₂ and optimized the intermediate reaction pathways.