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Issue 3, 2017
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CO/O2 assisted oxidative carbon–carbon and carbon–heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins

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Abstract

Selective carbon–carbon and carbon–heteroatom bond cleavage was achieved in a one reaction system. With this strategy a novel Pd/Cu-catalyzed aerobic oxidative oxosulfonation of olefins with DMSO has been developed. Preliminary mechanistic investigations indicated that CO/O2 assisted the bond cleavage and the leaving groups from the starting materials were trapped by O2 and underwent a hydroxylation process.

Graphical abstract: CO/O2 assisted oxidative carbon–carbon and carbon–heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins

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The article was received on 07 Oct 2016, accepted on 30 Nov 2016 and first published on 07 Dec 2016


Article type: Edge Article
DOI: 10.1039/C6SC04480H
Citation: Chem. Sci., 2017,8, 2175-2178
  • Open access: Creative Commons BY-NC license
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    CO/O2 assisted oxidative carbon–carbon and carbon–heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins

    A. Shao, M. Gao, S. Chen, T. Wang and A. Lei, Chem. Sci., 2017, 8, 2175
    DOI: 10.1039/C6SC04480H

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