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Issue 32, 2017, Issue in Progress
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Retrieving aromaticity of dithiadiazuliporphyrin by oxidation: illustration by experimental and theoretical investigation

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Abstract

The photophysical properties of neutral, monocation radical, and dication of dithiadiazuliporphyrin have been examined with a particular focus on their aromaticity. Dithiadiazuliporphyrin exhibits significantly different characteristics depending on its oxidation state. From these features, we could conclude that the aromaticity of dithiadiazuliporphyrin is changed from nonaromatic to aromatic upon oxidation from neutral to monocation radical and dication by Br2.

Graphical abstract: Retrieving aromaticity of dithiadiazuliporphyrin by oxidation: illustration by experimental and theoretical investigation

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Publication details

The article was received on 28 Feb 2017, accepted on 24 Mar 2017 and first published on 03 Apr 2017


Article type: Paper
DOI: 10.1039/C7RA02458D
Citation: RSC Adv., 2017,7, 19502-19505
  • Open access: Creative Commons BY license
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    Retrieving aromaticity of dithiadiazuliporphyrin by oxidation: illustration by experimental and theoretical investigation

    Y. M. Sung, N. Sprutta, J. O. Kim, Y. H. Koo, L. Latos-Grażyński and D. Kim, RSC Adv., 2017, 7, 19502
    DOI: 10.1039/C7RA02458D

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