Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

Jun Huang; Linyong Li; Haoguo Chen; Tiebo Xiao; Yuwei He; Lei Zhou

doi:10.1039/C6QO00813E

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Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide†

Jun Huang,^a Linyong Li,^a Haoguo Chen,^a Tiebo Xiao,^a Yuwei He^a and Lei Zhou

*^a

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* Corresponding authors

^a School of Chemistry, Sun Yat-Sen University, 135 Xingang West Road, Guangzhou, China
E-mail: zhoul39@mail.sysu.edu.cn

Abstract

A silver-catalyzed three-component reaction of diazoketones, anilines and NFSI is developed. The reaction provides a new method for gem-aminofluorination of acceptor diazo compounds with aniline as the nitrogen source and NFSI as the fluorine source.

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Article information

DOI: https://doi.org/10.1039/C6QO00813E
Article type: Research Article
Submitted: 14 Dec 2016
Accepted: 11 Jan 2017
First published: 12 Jan 2017

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Org. Chem. Front., 2017,4, 529-533

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Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

J. Huang, L. Li, H. Chen, T. Xiao, Y. He and L. Zhou, Org. Chem. Front., 2017, 4, 529 DOI: 10.1039/C6QO00813E

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Organic Chemistry Frontiers

Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide†

Abstract

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Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

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