Issue 24, 2017
From the journal:

Dalton Transactions

SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity†

Elisa Louyriac,a   Peter W. Roeskyb  and  Laurent Maron*a  

* Corresponding authors

a LPCNO, Université de Toulouse, CNRS, INSA, UPS, 135 avenue de Rangueil, 31077 Toulouse, France
E-mail: laurent.maron@irsamc.ups-tlse.fr

b Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, 76131 Karlsruhe, Germany
E-mail: roesky@kit.edu
Fax: +49 721 6084 4854

Abstract

Recently, it was shown that samarocene oxide [Cp*2Sm-O-SmCp*2] with Cp* = C5Me5 could react with organic and inorganic anhydrides. The reactions of [Cp*2Sm-O-SmCp*2] with SO2 and SO3 are reported using DFT calculations and compared with the reactivity of CO2. These reactions exhibit similar features yielding [Cp*2-Sm-(μ–η1:η2-OSO2)-SmCp*2] similar to [Cp*2-Sm-(μ–η1:η2-OCO2)-SmCp*2] and [Cp*2-Sm-(μ–η2:η2-O2SO2)-SmCp*2] complexes.

Graphical abstract: SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity

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Article information

DOI
https://doi.org/10.1039/C7DT01703K
Article type
Communication
Submitted
10 May 2017
Accepted
11 May 2017
First published
12 May 2017

Dalton Trans., 2017,46, 7660-7663

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SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity

E. Louyriac, P. W. Roesky and L. Maron, Dalton Trans., 2017, 46, 7660 DOI: 10.1039/C7DT01703K

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