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Issue 15, 2017
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Schiff base thorium(IV) and uranium(IV) chloro complexes: synthesis, substitution and oxidation chemistry

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Abstract

New tetradentate Schiff base chloro complexes of U(IV) and Th(IV) are prepared by salt metathesis approaches. These compounds undergo clean salt metathesis with NaN3 to generate stable pseudo-trans azide compounds. The uranium dichloro complex also undergoes 2 e oxidation with excess NaNO2 to generate the uranyl derivative. All classes of complexes are characterized by single crystal X-ray diffraction and NMR spectroscopy.

Graphical abstract: Schiff base thorium(iv) and uranium(iv) chloro complexes: synthesis, substitution and oxidation chemistry

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Publication details

The article was received on 16 Feb 2017, accepted on 22 Mar 2017 and first published on 23 Mar 2017


Article type: Communication
DOI: 10.1039/C7DT00580F
Citation: Dalton Trans., 2017,46, 4888-4892
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    Schiff base thorium(IV) and uranium(IV) chloro complexes: synthesis, substitution and oxidation chemistry

    B. C. Stobbe, D. R. Powell and R. K. Thomson, Dalton Trans., 2017, 46, 4888
    DOI: 10.1039/C7DT00580F

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