Jump to main content
Jump to site search

Issue 9, 2017
Previous Article Next Article

Ring opening of a sterically crowded 1,2-oxaphosphetane complex

Author affiliations

Abstract

The first example of a ring opening reaction of a 1,2-oxaphosphetane complex is reported, i.e., water in the presence of [Li(12-crown-4)]Cl furnished a C–OH functional phosphinito complex. Employment of the latter in ring forming reactions with Me2ECL2 (E = Si, Ge) using different nitrogen bases is also described.

Graphical abstract: Ring opening of a sterically crowded 1,2-oxaphosphetane complex

Back to tab navigation

Supplementary files

Publication details

The article was received on 12 Jan 2017, accepted on 03 Feb 2017 and first published on 14 Feb 2017


Article type: Paper
DOI: 10.1039/C7DT00136C
Citation: Dalton Trans., 2017,46, 2904-2909
  •   Request permissions

    Ring opening of a sterically crowded 1,2-oxaphosphetane complex

    A. W. Kyri, P. Brehm, G. Schnakenburg and R. Streubel, Dalton Trans., 2017, 46, 2904
    DOI: 10.1039/C7DT00136C

Search articles by author

Spotlight

Advertisements