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Issue 5, 2017
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Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states

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Abstract

The first examples of p-block coordination complexes of biquinoline, namely [(biq)BCl2]Cl and [(biq)BCl2]˙, were synthesized and structurally characterized. The acquired data allowed the estimation of the ligand charge state based on its metrical parameters. The subsequent use of this protocol, augmented with theoretical calculations, revealed ambiguities in the published data for transition metal complexes of biquinoline.

Graphical abstract: Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states

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Publication details

The article was received on 28 Nov 2016, accepted on 06 Jan 2017 and first published on 09 Jan 2017


Article type: Communication
DOI: 10.1039/C6DT04504A
Citation: Dalton Trans., 2017,46, 1377-1381
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    Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states

    J. Hurmalainen, A. Mansikkamäki, I. S. Morgan, A. Peuronen and H. M. Tuononen, Dalton Trans., 2017, 46, 1377
    DOI: 10.1039/C6DT04504A

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