Issue 1, 2017

Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

Abstract

Methodology for direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide under relatively mild conditions is demonstrated. The protocol utilizes packed bed flow reactors in series to couple rhenium catalyzed olefin epoxidation and aluminum catalyzed epoxide carboxylation in a single sequence.

Graphical abstract: Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

Supplementary files

Article information

Article type
Paper
Submitted
16 Sep 2016
Accepted
24 Nov 2016
First published
25 Nov 2016

Catal. Sci. Technol., 2017,7, 84-89

Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

A. A. Sathe, A. M. K. Nambiar and R. M. Rioux, Catal. Sci. Technol., 2017, 7, 84 DOI: 10.1039/C6CY01974A

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