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Issue 38, 2017
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Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound

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Abstract

Single crystal X-ray analysis at 100 K reveals that in the trigonal CCl4quasiracemic clathrate, space group R3, formed from host components S-(−)-Dianin's compound and its (+)-2R,4R 2-nor methyl analogue there is an unprecedented complete ordering of a C–Cl bond of the guest with respect to the c-axial direction. In this clathrate and that formed from the (+)-2R,4R and (+)-2R,4S epimers the participation of an unexpected host conformation is reported for the first time.

Graphical abstract: Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound

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Publication details

The article was received on 12 Jul 2017, accepted on 07 Aug 2017 and first published on 07 Aug 2017


Article type: Communication
DOI: 10.1039/C7CE01275F
Citation: CrystEngComm, 2017,19, 5703-5706
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    Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound

    C. S. Frampton, J. H. Gall and D. D. MacNicol, CrystEngComm, 2017, 19, 5703
    DOI: 10.1039/C7CE01275F

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