Low-cost CuNi@MIL-101 as an excellent catalyst toward cascade reaction: integration of ammonia borane dehydrogenation with nitroarene hydrogenation

Ying-Hua Zhou; Qihao Yang; Yu-Zhen Chen; Hai-Long Jiang

doi:10.1039/C7CC06530B

Low-cost CuNi@MIL-101 as an excellent catalyst toward cascade reaction: integration of ammonia borane dehydrogenation with nitroarene hydrogenation

Ying-Hua Zhou,^a^b Qihao Yang,^a Yu-Zhen Chen^a and Hai-Long Jiang*^a

Author affiliations

* Corresponding authors

^a Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China, Hefei, P. R. China
E-mail: jianglab@ustc.edu.cn

^b The Key Laboratory of Functional Molecular Solid, Ministry of Education, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, P. R. China

Abstract

Bimetallic CuNi nanoparticles (NPs) with low cost were rationally confined inside MIL-101 to give CuNi@MIL-101, which exhibits high efficiency and excellent recyclability toward the hydrogenation of nitroarenes under mild conditions on coupling with ammonia borane dehydrogenation. This is the first report on MOF-stabilized base metal NPs for cascade reactions.

Supplementary files

Publication details

The article was received on 19 Aug 2017, accepted on 24 Oct 2017 and first published on 24 Oct 2017

Article type: Communication

DOI: 10.1039/C7CC06530B

Citation: Chem. Commun., 2017,53, 12361-12364

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Low-cost CuNi@MIL-101 as an excellent catalyst toward cascade reaction: integration of ammonia borane dehydrogenation with nitroarene hydrogenation

Y. Zhou, Q. Yang, Y. Chen and H. Jiang, Chem. Commun., 2017, 53, 12361
DOI: 10.1039/C7CC06530B
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Chemical Communications

Low-cost CuNi@MIL-101 as an excellent catalyst toward cascade reaction: integration of ammonia borane dehydrogenation with nitroarene hydrogenation

Abstract

Supplementary files

Publication details

Low-cost CuNi@MIL-101 as an excellent catalyst toward cascade reaction: integration of ammonia borane dehydrogenation with nitroarene hydrogenation

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