Issue 81, 2017
From the journal:

Chemical Communications

High-pressure discovery of β-NiBi†

K. M. Powderly,‡a   S. M. Clarke,‡a   M. Amsler,§b   C. Wolverton, ORCID logo b   C. D. Malliakas,a   Y. Meng,c   S. D. Jacobsen ORCID logo d  and  D. E. Freedman ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA
E-mail: danna.freedman@northwestern.edu

b Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois, 60208, USA

c HPCAT, Geophysical Laboratory, Carnegie Institution of Washington, Argonne, Illinois, 60439, USA

d Department of Earth and Planetary Sciences, Northwestern University, Evanston, Illinois, 60208, USA

Abstract

Herein, we present the discovery of a new high-pressure phase in the Ni–Bi system, β-NiBi, which crystallizes in the TlI structure type. The powerful technique of in situ high-pressure and high-temperature powder X-ray diffraction enabled observation of the formation of β-NiBi and its reversible reconversion to the ambient pressure phase, α-NiBi.

Graphical abstract: High-pressure discovery of β-NiBi

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Article information

DOI
https://doi.org/10.1039/C7CC06471C
Article type
Communication
Submitted
17 Aug 2017
Accepted
22 Sep 2017
First published
22 Sep 2017

Chem. Commun., 2017,53, 11241-11244

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High-pressure discovery of β-NiBi

K. M. Powderly, S. M. Clarke, M. Amsler, C. Wolverton, C. D. Malliakas, Y. Meng, S. D. Jacobsen and D. E. Freedman, Chem. Commun., 2017, 53, 11241 DOI: 10.1039/C7CC06471C

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