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Issue 81, 2017
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High-pressure discovery of β-NiBi

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Abstract

Herein, we present the discovery of a new high-pressure phase in the Ni–Bi system, β-NiBi, which crystallizes in the TlI structure type. The powerful technique of in situ high-pressure and high-temperature powder X-ray diffraction enabled observation of the formation of β-NiBi and its reversible reconversion to the ambient pressure phase, α-NiBi.

Graphical abstract: High-pressure discovery of β-NiBi

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Publication details

The article was received on 17 Aug 2017, accepted on 22 Sep 2017 and first published on 22 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC06471C
Citation: Chem. Commun., 2017,53, 11241-11244
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    High-pressure discovery of β-NiBi

    K. M. Powderly, S. M. Clarke, M. Amsler, C. Wolverton, C. D. Malliakas, Y. Meng, S. D. Jacobsen and D. E. Freedman, Chem. Commun., 2017, 53, 11241
    DOI: 10.1039/C7CC06471C

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