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Issue 86, 2017
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Trapping of superoxido cobalt and peroxido dicobalt species formed reversibly from CoII and O2

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Abstract

The formation and spectroscopic characterization of a superoxido cobalt(III) and a peroxido dicobalt(III) species formed in the temperature dependent reversible reaction of a cobalt(II) precursor with O2 is described. The electronic nature of each species is explored in their reactivity with organic substrates.

Graphical abstract: Trapping of superoxido cobalt and peroxido dicobalt species formed reversibly from CoII and O2

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Publication details

The article was received on 28 Jul 2017, accepted on 09 Oct 2017 and first published on 16 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC05904C
Citation: Chem. Commun., 2017,53, 11782-11785
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    Trapping of superoxido cobalt and peroxido dicobalt species formed reversibly from CoII and O2

    T. Corona, S. K. Padamati, F. Acuña-Parés, C. Duboc, W. R. Browne and A. Company, Chem. Commun., 2017, 53, 11782
    DOI: 10.1039/C7CC05904C

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