Issue 59, 2017

An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

Abstract

We report a triazole-based trinuclear complex as the first example that displays a complete one-step first-order [HS–HS–HS] ↔ [LS–LS–LS] spin transition at 318 K. The strong ferro-elastic interactions, between the three metal centers, have been identified as the source of the concerted spin transition in this trinuclear complex.

Graphical abstract: An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

Supplementary files

Article information

Article type
Communication
Submitted
27 May 2017
Accepted
30 Jun 2017
First published
30 Jun 2017

Chem. Commun., 2017,53, 8356-8359

An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

N. Pittala, F. Thétiot, C. Charles, S. Triki, K. Boukheddaden, G. Chastanet and M. Marchivie, Chem. Commun., 2017, 53, 8356 DOI: 10.1039/C7CC04112H

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