Issue 73, 2017
From the journal:

Chemical Communications

A highly crystalline oriented metal–organic framework thin film with an inorganic pillar†

Yuki Watanabe,a   Tomoyuki Haraguchi, ORCID logo ‡a   Kazuya Otsubo, ORCID logo *a   Osami Sakata, ORCID logo b   Akihiko Fujiwara ORCID logo c  and  Hiroshi Kitagawa ORCID logo *ade  

* Corresponding authors

a Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto, Japan
E-mail: kazuya@kuchem.kyoto-u.ac.jp, kitagawa@kuchem.kyoto-u.ac.jp

b Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan

c School of Science and Technology, Kwansai Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan

d Institute for Integrated Cell-Material Science (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

e INAMORI Frontier Research Center, Kyushu University, 774 Motooka, Nishi-ku, Fukuoka 819-3095, Japan

Abstract

We report a step-by-step route to fabricate the first example of a crystalline oriented metal–organic framework thin film having an anionic inorganic pillar ligand, {Cu(4,4′-bipyridyl)2(SiF6)}. X-ray study and sorption analysis revealed its high crystallinity and porous character.

Graphical abstract: A highly crystalline oriented metal–organic framework thin film with an inorganic pillar

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Article information

DOI
https://doi.org/10.1039/C7CC03828C
Article type
Communication
Submitted
17 May 2017
Accepted
24 Aug 2017
First published
24 Aug 2017

Chem. Commun., 2017,53, 10112-10115

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A highly crystalline oriented metal–organic framework thin film with an inorganic pillar

Y. Watanabe, T. Haraguchi, K. Otsubo, O. Sakata, A. Fujiwara and H. Kitagawa, Chem. Commun., 2017, 53, 10112 DOI: 10.1039/C7CC03828C

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