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Issue 59, 2017
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A silver(I)-induced higher-ordered structure based on planar chiral tetrasubstituted [2.2]paracyclophane

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Abstract

Optically active phenylene–ethynylene dimers with pyridine groups based on a planar chiral 4,7,12,15-tetrasubstituted [2.2]paracyclophane were synthesized. The chiral conformation was controlled by pyridine–Ag(I) coordinations. After Ag(I) coordination, the resulting higher-ordered structure dramatically enhanced the signal intensity of circular dichroism (CD) and decreased that of circularly polarized luminescence (CPL).

Graphical abstract: A silver(i)-induced higher-ordered structure based on planar chiral tetrasubstituted [2.2]paracyclophane

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Publication details

The article was received on 09 May 2017, accepted on 28 Jun 2017 and first published on 28 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03615A
Citation: Chem. Commun., 2017,53, 8304-8307
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    A silver(I)-induced higher-ordered structure based on planar chiral tetrasubstituted [2.2]paracyclophane

    M. Gon, Y. Morisaki and Y. Chujo, Chem. Commun., 2017, 53, 8304
    DOI: 10.1039/C7CC03615A

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