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Issue 55, 2017
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Thermal decomposition pathways of nitro-functionalized metal–organic frameworks

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Abstract

The decomposition behavior of high energy metal–organic frameworks (MOFs) with extensive nitration is disclosed. In contrast to the detonation behavior observed in molecular energetic compounds, deflagration transforms cubic MOFs into anisotropic carbon structures with highly dispersed metal. Both the structural metal and intimate mixing are found to be critical.

Graphical abstract: Thermal decomposition pathways of nitro-functionalized metal–organic frameworks

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Publication details

The article was received on 02 May 2017, accepted on 21 Jun 2017 and first published on 21 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03354K
Citation: Chem. Commun., 2017,53, 7808-7811
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    Thermal decomposition pathways of nitro-functionalized metal–organic frameworks

    K. A. McDonald, N. Ko, K. Noh, J. C. Bennion, J. Kim and A. J. Matzger, Chem. Commun., 2017, 53, 7808
    DOI: 10.1039/C7CC03354K

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