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Issue 48, 2017
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A chimeric design of heterospin 2p–3d, 2p–4f, and 2p–3d–4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands

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Abstract

End-off bicompartmental ligands bearing a nitronyl–nitroxide arm have been designed for synthesizing various heterospin molecular systems. These ligands can selectively interact with 3d and 4f metal ions, leading to 2p–4f, 2p–3d, and 2p–3d–4f complexes. The magnetic properties of the 2p–4f and 2p–3d–4f complexes have been investigated and rationalized by theoretical calculations.

Graphical abstract: A chimeric design of heterospin 2p–3d, 2p–4f, and 2p–3d–4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands

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Publication details

The article was received on 27 Apr 2017, accepted on 23 May 2017 and first published on 23 May 2017


Article type: Communication
DOI: 10.1039/C7CC03236F
Citation: Chem. Commun., 2017,53, 6504-6507
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    A chimeric design of heterospin 2p–3d, 2p–4f, and 2p–3d–4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands

    A. A. Patrascu, S. Calancea, M. Briganti, S. Soriano, A. M. Madalan, R. A. A. Cassaro, A. Caneschi, F. Totti, M. G. F. Vaz and M. Andruh, Chem. Commun., 2017, 53, 6504
    DOI: 10.1039/C7CC03236F

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