Issue 36, 2017
From the journal:

Chemical Communications

Synthesis and characterization of a dipyriamethyrin–uranyl complex†

James T. Brewster, II, ORCID logo a   Qing He,a   Gonzalo Anguera,a   Matthew D. Moore, ORCID logo a   Xian-Sheng Ke, ORCID logo a   Vincent M. Lyncha  and  Jonathan L. Sessler ORCID logo *a  

* Corresponding authors

a Department of Chemistry, The University of Texas at Austin, 105 East 24th, Street-Stop A5300, Austin, Texas, USA
E-mail: sessler@cm.utexas.edu

Abstract

The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

Graphical abstract: Synthesis and characterization of a dipyriamethyrin–uranyl complex

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Article information

DOI
https://doi.org/10.1039/C7CC01674C
Article type
Communication
Submitted
03 Mar 2017
Accepted
10 Apr 2017
First published
12 Apr 2017

Chem. Commun., 2017,53, 4981-4984

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Synthesis and characterization of a dipyriamethyrin–uranyl complex

J. T. Brewster, Q. He, G. Anguera, M. D. Moore, X. Ke, V. M. Lynch and J. L. Sessler, Chem. Commun., 2017, 53, 4981 DOI: 10.1039/C7CC01674C

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