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Issue 18, 2017
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An unexpected pathway for hydrodesulfurization of gazole over a CoMoS active phase supported on a mesoporous TiO2 catalyst

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Abstract

Using dual mesoporous titania as a support, due to the presence of intrinsic Brönsted acid sites, the main approach to 4,6-dimethylbenzothiophene (46DMDBT) hydrodesulfurization (HDS) becomes the direct desulfurization (DDS) route through isomerization and dismutation reactions, instead of the hydrogenation (HYD) pathway usually observed with a conventional promoted (by Ni or Co) MoS2/Al2O3 catalyst.

Graphical abstract: An unexpected pathway for hydrodesulfurization of gazole over a CoMoS active phase supported on a mesoporous TiO2 catalyst

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Publication details

The article was received on 01 Feb 2017, accepted on 06 Feb 2017 and first published on 06 Feb 2017


Article type: Communication
DOI: 10.1039/C7CC00848A
Citation: Chem. Commun., 2017,53, 2717-2720
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    An unexpected pathway for hydrodesulfurization of gazole over a CoMoS active phase supported on a mesoporous TiO2 catalyst

    I. Naboulsi, C. Felipe Linares Aponte, B. Lebeau, S. Brunet, L. Michelin, M. Bonne and J. L. Blin, Chem. Commun., 2017, 53, 2717
    DOI: 10.1039/C7CC00848A

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