A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry

Yinli Zhang; Sheng Zhang; Lin Sun; Qi Yang; Jing Han; Qing Wei; Gang Xie; Sanping Chen; Shengli Gao

doi:10.1039/C7CC00545H

A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry

Yinli Zhang,^a^b Sheng Zhang,^a^c Lin Sun,^a Qi Yang,^a Jing Han,^a Qing Wei,^a Gang Xie,^a Sanping Chen*^a and Shengli Gao^a

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* Corresponding authors

^a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, China
E-mail: sanpingchen@126.com

^b Department of Chemistry, Xianyang Normal University, Xian'yang, P. R. China

^c College of Chemistry and Chemical Engineering, Baoji University of Arts and Science, 1 Hi-Tech Avenue, Baoji, China

Abstract

It is a tremendous challenge to prepare solvent-free dense energetic metal–organic frameworks (EMOFs), hence also to improve their stability and energetic performance. In this study, based on in situ microcalorimetry, an interpenetrating EMOF without solvent molecules, [Cu(tztr)]_n (1, H₂tztr = 3-(tetrazol-5-yl)triazole) was obtained, possessing high stability (T_dec = 360 °C) and outstanding energetic properties (ΔH_det = 7.53 kcal cm⁻³, D = 8.429 km s⁻¹, P = 40.02 GPa).

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Publication details

The article was received on 20 Jan 2017, accepted on 16 Feb 2017 and first published on 17 Feb 2017

Article type: Communication

DOI: 10.1039/C7CC00545H

Citation: Chem. Commun., 2017,53, 3034-3037

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A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry

Y. Zhang, S. Zhang, L. Sun, Q. Yang, J. Han, Q. Wei, G. Xie, S. Chen and S. Gao, Chem. Commun., 2017, 53, 3034
DOI: 10.1039/C7CC00545H
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Yinli Zhang

Sheng Zhang

Lin Sun

Qi Yang

Jing Han

Qing Wei

Gang Xie

Sanping Chen

Shengli Gao

Chemical Communications

A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry

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A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry

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