Issue 20, 2017
From the journal:

Chemical Communications

An efficient noble-metal-free supported copper catalyst for selective nitrocyclohexane hydrogenation to cyclohexanone oxime†

Qian-Qian Zhang,a   Jing Dong,ab   Yong-Mei Liu, ORCID logo *a   Yong Cao,a   He-Yong Hea  and  Yang-Dong Wang*b  

* Corresponding authors

a Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China
E-mail: ymliu@fudan.edu.cn

b SINOPEC Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, P. R. China
E-mail: wangyd.sshy@sinopec.com

Abstract

It was shown for the first time that cyclohexanone oxime (CHO) can be selectively produced by heterogeneous copper-catalyzed hydrogenative transformation of nitrocyclohexane (NC). The combination of Cu0 and Cu+ and their cooperative interaction with weakly acidic SiO2 supports elicited a significantly unique and selective catalysis in the hydrogenation of NC to CHO.

Graphical abstract: An efficient noble-metal-free supported copper catalyst for selective nitrocyclohexane hydrogenation to cyclohexanone oxime

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Article information

DOI
https://doi.org/10.1039/C6CC10267K
Article type
Communication
Submitted
03 Jan 2017
Accepted
13 Feb 2017
First published
13 Feb 2017

Chem. Commun., 2017,53, 2930-2933

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An efficient noble-metal-free supported copper catalyst for selective nitrocyclohexane hydrogenation to cyclohexanone oxime

Q. Zhang, J. Dong, Y. Liu, Y. Cao, H. He and Y. Wang, Chem. Commun., 2017, 53, 2930 DOI: 10.1039/C6CC10267K

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