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Issue 6, 2017
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Enhancing the low-energy absorption band and charge mobility of antiaromatic NiII norcorroles by their substituent effects

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Abstract

Dissymmetrical substitution of norcorrole enables the preparation of various norcorrole derivatives as air- and moisture-stable species. Intramolecular charge transfer interactions between electron-donating substituents and the norcorrole core in these norcorroles significantly enhanced their low-energy absorption bands, which were forbidden in symmetrical NiII dimesitylnorcorrole.

Graphical abstract: Enhancing the low-energy absorption band and charge mobility of antiaromatic NiII norcorroles by their substituent effects

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Publication details

The article was received on 26 Nov 2016, accepted on 20 Dec 2016 and first published on 21 Dec 2016


Article type: Communication
DOI: 10.1039/C6CC09444A
Citation: Chem. Commun., 2017,53, 1112-1115
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    Enhancing the low-energy absorption band and charge mobility of antiaromatic NiII norcorroles by their substituent effects

    T. Yoshida, D. Sakamaki, S. Seki and H. Shinokubo, Chem. Commun., 2017, 53, 1112
    DOI: 10.1039/C6CC09444A

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