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Issue 12, 2017
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meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine

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Abstract

The selective alkylation of a single meso-N atom of a corrolazine macrocycle is reported. Alkylation has a dramatic impact on the physicochemical properties of ReV(O)(TBP8Cz). New electron-transfer and hydrogen-atom-transfer reactivity is also seen for this complex, including one-electron reduction, which gives an air-stable 19π-electron aromatic radical complex.

Graphical abstract: meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine

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Publication details

The article was received on 23 Nov 2016, accepted on 28 Dec 2016 and first published on 25 Jan 2017


Article type: Communication
DOI: 10.1039/C6CC09341H
Citation: Chem. Commun., 2017,53, 1961-1964
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    meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine

    E. E. Joslin, J. P. T. Zaragoza, M. A. Siegler and D. P. Goldberg, Chem. Commun., 2017, 53, 1961
    DOI: 10.1039/C6CC09341H

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