Issue 12, 2017
From the journal:

Chemical Communications

Metal-induced supramolecular chirality inversion of small self-assembled molecules in solution†

Zoran Kokan,*a   Berislav Perić,a   Mario Vazdar,a   Željko Marinić,a   Dražen Vikić-Topić,a   Ernest Meštrovićb  and  Srećko I. Kirin ORCID logo *a  

* Corresponding authors

a Ruđer Bošković Institute, Bijenička c. 54, 10000 Zagreb, Croatia
E-mail: zoran.kokan@irb.hr, srecko.kirin@irb.hr

b PLIVA Croatia d.o.o., Prilaz baruna Filipovića 25, 10000 Zagreb, Croatia

Abstract

A non-covalent self-assembled chiral alanyl aminopyridine ligand exhibits supramolecular chirality in solution, independent of the organic solvent used. The supramolecular chirality of the assemblies is completely inverted by complexation to zinc ions. To date, such a supramolecular metal–ligand system has not been reported in the literature.

Graphical abstract: Metal-induced supramolecular chirality inversion of small self-assembled molecules in solution

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Article information

DOI
https://doi.org/10.1039/C6CC09203A
Article type
Communication
Submitted
17 Nov 2016
Accepted
11 Jan 2017
First published
11 Jan 2017

Chem. Commun., 2017,53, 1945-1948

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Metal-induced supramolecular chirality inversion of small self-assembled molecules in solution

Z. Kokan, B. Perić, M. Vazdar, Ž. Marinić, D. Vikić-Topić, E. Meštrović and S. I. Kirin, Chem. Commun., 2017, 53, 1945 DOI: 10.1039/C6CC09203A

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