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Issue 6, 2017
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Bis(amidinate) ligands in early lanthanide chemistry – synthesis, structures, and hydroamination catalysis

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Abstract

Bis(amidinate) ligands attached to rigid dibenzofuran and phenanthrene backbones have been introduced into lanthanide chemistry for the first time. Depending on the ligand and on the lanthanide source, either bi- and tetra-metallic macrocycles or monometallic complexes were obtained. The mono- and bi-metallic systems were compared in terms of their reactivity in the intramolecular hydroamination reaction. Depending on the catalyst used (mono vs. bimetallic) different rate laws were observed.

Graphical abstract: Bis(amidinate) ligands in early lanthanide chemistry – synthesis, structures, and hydroamination catalysis

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Publication details

The article was received on 09 Nov 2016, accepted on 19 Dec 2016 and first published on 03 Jan 2017


Article type: Communication
DOI: 10.1039/C6CC08958E
Citation: Chem. Commun., 2017,53, 1060-1063
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    Bis(amidinate) ligands in early lanthanide chemistry – synthesis, structures, and hydroamination catalysis

    N. Kazeminejad, D. Munzel, M. T. Gamer and P. W. Roesky, Chem. Commun., 2017, 53, 1060
    DOI: 10.1039/C6CC08958E

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