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Issue 18, 2017
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Elucidating light-induced charge accumulation in an artificial analogue of methane monooxygenase enzymes using time-resolved X-ray absorption spectroscopy

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Abstract

We report the use of time-resolved X-ray absorption spectroscopy in the ns–μs time scale to track the light induced two electron transfer processes in a multi-component photocatalytic system, consisting of [Ru(bpy)3]2+/ a diiron(III,III) model/triethylamine. EXAFS analysis with DFT calculations confirms the structural configurations of the diiron(III,III) and reduced diiron(II,II) states.

Graphical abstract: Elucidating light-induced charge accumulation in an artificial analogue of methane monooxygenase enzymes using time-resolved X-ray absorption spectroscopy

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Publication details

The article was received on 01 Nov 2016, accepted on 08 Feb 2017 and first published on 08 Feb 2017


Article type: Communication
DOI: 10.1039/C6CC08748E
Citation: Chem. Commun., 2017,53, 2725-2728
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    Elucidating light-induced charge accumulation in an artificial analogue of methane monooxygenase enzymes using time-resolved X-ray absorption spectroscopy

    D. Moonshiram, A. Picón, A. Vazquez-Mayagoitia, X. Zhang, M. Tu, P. Garrido-Barros, J. Mahy, F. Avenier and A. Aukauloo, Chem. Commun., 2017, 53, 2725
    DOI: 10.1039/C6CC08748E

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