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Issue 5, 2017
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Proton-driven coordination-induced spin state switch (PD-CISSS) of iron(II) complexes

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Abstract

Here we report the completely reversible spin state switch of the naturally diamagnetic tris(bipyridine)iron(II) complex and the spin crossover complex bis(2,6-bis(1H-pyrazol-3-yl)pyridine)iron(II) by the variation of the pH followed by 1H-NMR, UV-Vis spectroscopy, and magnetic and relaxivity measurements in solution and as composite materials encapsulated in a zeolite matrix.

Graphical abstract: Proton-driven coordination-induced spin state switch (PD-CISSS) of iron(ii) complexes

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Publication details

The article was received on 26 Oct 2016, accepted on 15 Dec 2016 and first published on 15 Dec 2016


Article type: Communication
DOI: 10.1039/C6CC08618G
Citation: Chem. Commun., 2017,53, 971-974
  • Open access: Creative Commons BY license
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    Proton-driven coordination-induced spin state switch (PD-CISSS) of iron(II) complexes

    R. Nowak, E. A. Prasetyanto, L. De Cola, B. Bojer, R. Siegel, J. Senker, E. Rössler and B. Weber, Chem. Commun., 2017, 53, 971
    DOI: 10.1039/C6CC08618G

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