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Issue 4, 2017
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Degradable fluorescent single-chain nanoparticles based on metathesis polymers

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Abstract

We introduce the facile synthesis of fluorescent single-chain nanoparticles (SCNPs) based on chain-shattering acyclic diene metathesis (ADMET) polymers featuring self-immolative azobenzene motifs. An electrophilic alkoxyetherification is utilized to introduce the photoreactive moieties required for the subsequent chain collapse via UV-induced nitrile imine-mediated tetrazole–ene cycloaddition (NITEC).

Graphical abstract: Degradable fluorescent single-chain nanoparticles based on metathesis polymers

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Publication details

The article was received on 24 Oct 2016, accepted on 12 Dec 2016 and first published on 14 Dec 2016


Article type: Communication
DOI: 10.1039/C6CC08554G
Citation: Chem. Commun., 2017,53, 775-778
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    Degradable fluorescent single-chain nanoparticles based on metathesis polymers

    J. T. Offenloch, J. Willenbacher, P. Tzvetkova, C. Heiler, H. Mutlu and C. Barner-Kowollik, Chem. Commun., 2017, 53, 775
    DOI: 10.1039/C6CC08554G

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