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Issue 7, 2016
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Band gap and work function tailoring of SnO2 for improved transparent conducting ability in photovoltaics

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Abstract

Transparent conducting oxides (TCOs) are an essential component in modern optoelectronic devices, such as solar panels and touch screens. Their ability to combine transparency and conductivity, two properties that are normally mutually exclusive, have made them the subject of intense research over the last 50 years. SnO2, doped with F or Sb, is a widely used and relatively inexpensive transparent conducting material, however, its electronic structure leaves scope for improving its properties for use in many TCO applications, especially in solar cell devices. Here we show using density functional theory that incorporation of Pb into SnO2 reduces the band gap through lowering of the conduction band minimum, thereby increasing the electron affinity. The electron effective mass at the conduction band minimum decreases alongside the band gap, indicating improved charge carrier mobilities. Furthermore, the calculated optical absorption properties show the alloys retain their transparency in the visible spectrum. Our results suggest that alloying of PbO2 with SnO2 will enable improved electronic properties, including a highly tuneable workfunction, which will open up the material for other applications, such as hole injection layers in organic photovoltaics.

Graphical abstract: Band gap and work function tailoring of SnO2 for improved transparent conducting ability in photovoltaics

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Publication details

The article was received on 03 Dec 2015, accepted on 14 Jan 2016 and first published on 14 Jan 2016


Article type: Paper
DOI: 10.1039/C5TC04089B
Citation: J. Mater. Chem. C, 2016,4, 1467-1475
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    Band gap and work function tailoring of SnO2 for improved transparent conducting ability in photovoltaics

    A. M. Ganose and D. O. Scanlon, J. Mater. Chem. C, 2016, 4, 1467
    DOI: 10.1039/C5TC04089B

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      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
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