Morphology and crystal phase evolution induced performance enhancement of MnO2 grown on reduced graphene oxide for lithium ion batteries

Abstract

MnO₂ nanorods grown on reduced graphene oxide (MnO₂-NR/rGO) have been synthesized through a hydrothermal treatment of the reaction product between KMnO₄ and 2-(N-morpholino)ethanesulfonic acid in the presence of graphene oxide. When tested as an anode in a lithium-ion battery (LIB), the obtained MnO₂-NR/rGO exhibits a significant enhancement in electrochemical performance, especially after being discharged/charged for 300 cycles. Characterization of the microscopic features suggests that the morphology and crystal structure of the MnO₂ nanorods evolve gradually during cycling, transforming the product of the MnO₂-NR/rGO into a unique electrode architecture consisting of well-separated rGO coated with well-crystallized λ-MnO₂ after 300 cycles. The significantly enhanced electrochemical performance of the MnO₂-NR/rGO electrode after 300 cycles is attributed mainly to the resulting electrode architecture, which enhances the interaction between MnO₂ and rGO, reduces the charge transfer resistance across the MnO₂/rGO interface, and makes the rGO readily accessible to lithium ion storage. The demonstrated specific capacity and rate capability are among the best ever reported for transition metal oxide based electrodes for LIBs.