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Issue 6, 2016
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Palladium-catalyzed incorporation of atmospheric CO2: efficient synthesis of functionalized oxazolidinones

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Abstract

Methods to incorporate atmospheric CO2 into organic molecules are on demand. Here we present two Pd-catalyzed multicomponent reactions that provide functionalized oxazolidinones from propargylamines, aryl halides and CO2 as starting materials. These transformations, devoid of high CO2 pressures, represent a streamlined stereocontrolled synthesis of previously inaccessible versions of these useful heterocycles in an atom-economic manner, as up to four new single bonds are formed in a single synthetic operation.

Graphical abstract: Palladium-catalyzed incorporation of atmospheric CO2: efficient synthesis of functionalized oxazolidinones

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Publication details

The article was received on 27 Jan 2016, accepted on 03 Mar 2016 and first published on 10 Mar 2016


Article type: Edge Article
DOI: 10.1039/C6SC00419A
Citation: Chem. Sci., 2016,7, 3914-3918
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    Palladium-catalyzed incorporation of atmospheric CO2: efficient synthesis of functionalized oxazolidinones

    P. García-Domínguez, L. Fehr, G. Rusconi and C. Nevado, Chem. Sci., 2016, 7, 3914
    DOI: 10.1039/C6SC00419A

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