Issue 80, 2016
From the journal:

RSC Advances

Synthesis and catalytic activity of ruthenium indenylidene complexes bearing unsymmetrical NHC containing a heteroaromatic moiety†

Michał Smoleń,a   Wioletta Kośnik,a   Rafał Loska,b   Roman Gajda,a   Maura Malińska,a   Krzysztof Woźniaka  and  Karol Grela*a  

* Corresponding authors

a Biological and Chemical Research Centre, Faculty of Chemistry, University of Warsaw, Żwirki i Wigury Street 101, 02-089 Warszawa, Poland
E-mail: klgrela@gmail.com
Web: http://karolgrela.eu/

b Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

Abstract

New robust and air stable ruthenium(II) indenylidene second generation olefin metathesis catalysts with unsymmetrical N-heterocyclic carbene (NHC) ligands were synthesized. Model metathesis reactions were performed in the presence of newly-developed complexes in commercial grade toluene under air, leading to high conversions and good selectivities.

Graphical abstract: Synthesis and catalytic activity of ruthenium indenylidene complexes bearing unsymmetrical NHC containing a heteroaromatic moiety

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Article information

DOI
https://doi.org/10.1039/C6RA18210K
Article type
Paper
Submitted
17 Jul 2016
Accepted
08 Aug 2016
First published
08 Aug 2016

RSC Adv., 2016,6, 77013-77019

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Synthesis and catalytic activity of ruthenium indenylidene complexes bearing unsymmetrical NHC containing a heteroaromatic moiety

M. Smoleń, W. Kośnik, R. Loska, R. Gajda, M. Malińska, K. Woźniak and K. Grela, RSC Adv., 2016, 6, 77013 DOI: 10.1039/C6RA18210K

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