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Issue 80, 2016
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Synthesis and catalytic activity of ruthenium indenylidene complexes bearing unsymmetrical NHC containing a heteroaromatic moiety

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Abstract

New robust and air stable ruthenium(II) indenylidene second generation olefin metathesis catalysts with unsymmetrical N-heterocyclic carbene (NHC) ligands were synthesized. Model metathesis reactions were performed in the presence of newly-developed complexes in commercial grade toluene under air, leading to high conversions and good selectivities.

Graphical abstract: Synthesis and catalytic activity of ruthenium indenylidene complexes bearing unsymmetrical NHC containing a heteroaromatic moiety

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Publication details

The article was received on 17 Jul 2016, accepted on 08 Aug 2016 and first published on 08 Aug 2016


Article type: Paper
DOI: 10.1039/C6RA18210K
Citation: RSC Adv., 2016,6, 77013-77019
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    Synthesis and catalytic activity of ruthenium indenylidene complexes bearing unsymmetrical NHC containing a heteroaromatic moiety

    M. Smoleń, W. Kośnik, R. Loska, R. Gajda, M. Malińska, K. Woźniak and K. Grela, RSC Adv., 2016, 6, 77013
    DOI: 10.1039/C6RA18210K

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