A visible light-induced decarboxylative amination of indoline-2-carboxylic acids and azodicarboxylate esters has been developed, in which the oxidation of α-amino acids provides a versatile CO2-extrusion platform to generate α-aminoalkyl radicals. The corresponding products were obtained with yields of up to 72% catalyzed by a metal-free photocatalyst under mild conditions.
The article was received on 08 Jul 2016, accepted on 07 Oct 2016 and first published on 07 Oct 2016
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