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Issue 85, 2016, Issue in Progress
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Synthesis and solid-state fluorescence of aryl substituted 2-halogenocinchomeronic dinitriles

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Abstract

Based on the reaction of available adducts of tetracyanoethylene (TCNE) and aromatic ketones (4-aryl-4-oxoalkane-1,1,2,2-tetracarbonitriles) with hydrogen chloride, several aryl substituted 2-halogencinchomeronic dinitriles were synthesized. We found that aryl substituted derivatives, in contrast to alkyl substituted ones, possess an intensive solid state fluorescence. The relationship between the chemical structures and photophysical properties of these compounds was investigated.

Graphical abstract: Synthesis and solid-state fluorescence of aryl substituted 2-halogenocinchomeronic dinitriles

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Publication details

The article was received on 29 Jun 2016, accepted on 12 Aug 2016 and first published on 15 Aug 2016


Article type: Paper
DOI: 10.1039/C6RA16787J
Citation: RSC Adv., 2016,6, 82227-82232
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    Synthesis and solid-state fluorescence of aryl substituted 2-halogenocinchomeronic dinitriles

    O. V. Ershov, M. Yu. Ievlev, M. Yu. Belikov, K. V. Lipin, A. I. Naydenova and V. A. Tafeenko, RSC Adv., 2016, 6, 82227
    DOI: 10.1039/C6RA16787J

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