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Issue 61, 2016, Issue in Progress
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MOF-253-Pd(OAc)2: a recyclable MOF for transition-metal catalysis in water

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Abstract

We report palladium(II)-functionalized MOF-253 (MOF-253-Pd(OAc)2) as a recyclable catalyst to form all-carbon quaternary centers via conjugate additions of arylboronic acids to β,β-disubstituted enones in aqueous media. We demonstrate MOF-253-Pd(OAc)2 can be reused 8 times to form ketone products in yields above 75% while maintaining its crystallinity. Additions of a range of stereoelectronically diverse arylboronic acids to a variety of β,β-disubstituted enones catalyzed by MOF-253-Pd(OAc)2 occur in modest-to-high yields (34–95%).

Graphical abstract: MOF-253-Pd(OAc)2: a recyclable MOF for transition-metal catalysis in water

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Publication details

The article was received on 16 May 2016, accepted on 04 Jun 2016 and first published on 06 Jun 2016


Article type: Communication
DOI: 10.1039/C6RA12746K
Author version available: Download Author version (PDF)
Citation: RSC Adv., 2016,6, 56330-56334
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    MOF-253-Pd(OAc)2: a recyclable MOF for transition-metal catalysis in water

    R. Van Zeeland, X. Li, W. Huang and L. M. Stanley, RSC Adv., 2016, 6, 56330
    DOI: 10.1039/C6RA12746K

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