The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds

Hamid Reza Khavasi; Alireza Ghanbarpour; Alireza Azhdari Tehrani

doi:10.1039/C5RA25192C

The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds

Hamid Reza Khavasi,*^a Alireza Ghanbarpour^a and Alireza Azhdari Tehrani^a

Author affiliations

* Corresponding authors

^a Faculty of Chemistry, Shahid Beheshti University, Evin, Tehran 1983963113, Iran
E-mail: h-khavasi@sbu.ac.ir

Abstract

A series of four new manganese(II) complexes based on the L^4-X ligand, where L is N-(4-halo)phenyl picolinamide ligands, have been synthesized, characterized and their supramolecular crystal structures were studied by geometrical analysis and theoretical calculation. Our study reveals the role of weak intermolecular interactions involving halogens, such as C–H⋯X hydrogen bonds (in the cases of 1 and 2) and C–X⋯X′–M halogen bonds (in the cases of 3 and 4), in the structural changes of supramolecular assemblies of coordination compounds. This study could provide further insight into discovering the role of weak intermolecular interactions in the context of metallosupramolecular assembly.

Supplementary files

Publication details

The article was received on 26 Nov 2015, accepted on 16 Dec 2015 and first published on 18 Dec 2015

Article type: Paper

DOI: 10.1039/C5RA25192C

Author version available: Download Author version (PDF)

Citation: RSC Adv., 2016,6, 2422-2430

Request permissions
The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds

H. R. Khavasi, A. Ghanbarpour and A. A. Tehrani, RSC Adv., 2016, 6, 2422
DOI: 10.1039/C5RA25192C
If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using RightsLink. Go to our Instructions for using RightsLink page for details.

Authors contributing to RSC publications (journal articles, books or book chapters) do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:
For reproduction of material from NJC:
Reproduced from Ref. XX with permission from the Centre National de la Recherche Scientifique (CNRS) and The Royal Society of Chemistry.

For reproduction of material from PCCP:
Reproduced from Ref. XX with permission from the PCCP Owner Societies.

For reproduction of material from PPS:
Reproduced from Ref. XX with permission from the European Society for Photobiology, the European Photochemistry Association, and The Royal Society of Chemistry.

For reproduction of material from all other RSC journals and books:
Reproduced from Ref. XX with permission from The Royal Society of Chemistry.
If the material has been adapted instead of reproduced from the original RSC publication "Reproduced from" can be substituted with "Adapted from".

In all cases the Ref. XX is the XXth reference in the list of references.

If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. contained in this article in third party publications or in a thesis or dissertation provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:
For reproduction of material from NJC:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC

For reproduction of material from PCCP:
[Original citation] - Reproduced by permission of the PCCP Owner Societies

For reproduction of material from PPS:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC

For reproduction of material from all other RSC journals:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry
If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

RSC Advances

The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds

Abstract

Supplementary files

Publication details

The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds

Search articles by author

Spotlight

Advertisements