Issue 8, 2016

Iron-catalyzed trifluoromethylation of vinylcyclopropanes: facile synthesis of CF3–containing dihydronaphthalene derivatives

Abstract

An efficient Fe(II)-catalyzed trifluoromethylation of vinylcyclopropanes was successfully developed. A series of CF3-containing dihydronaphthalene derivatives were prepared in moderate to high yields (up to 96%) under mild reaction conditions using the Togni reagent as the CF3 source.

Graphical abstract: Iron-catalyzed trifluoromethylation of vinylcyclopropanes: facile synthesis of CF3–containing dihydronaphthalene derivatives

Supplementary files

Article information

Article type
Research Article
Submitted
19 Apr 2016
Accepted
20 May 2016
First published
23 May 2016

Org. Chem. Front., 2016,3, 934-938

Iron-catalyzed trifluoromethylation of vinylcyclopropanes: facile synthesis of CF3–containing dihydronaphthalene derivatives

Z. Li, X. Bao, J. Sun, J. Shen, D. Wu, Y. Liu, Q. Deng and F. Liu, Org. Chem. Front., 2016, 3, 934 DOI: 10.1039/C6QO00166A

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