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Issue 4, 2016
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Primary alkyl bis-catecholato silicates in dual photoredox/nickel catalysis: aryl- and heteroaryl-alkyl cross coupling reactions

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Abstract

Primary alkyl bis-catecholato silicates have been successfully engaged with aryl and heteroaryl bromide substrates in photoredox/nickel dual catalysis to provide aryl- and heteroaryl-alkyl cross coupling products. The scope of the transformation is wide and the process appears to be tolerant of various functional groups present. Of note, most examples rely on the challenging use of highly reactive primary radicals which constitutes a significant advance in these cross coupling reactions.

Graphical abstract: Primary alkyl bis-catecholato silicates in dual photoredox/nickel catalysis: aryl- and heteroaryl-alkyl cross coupling reactions

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Publication details

The article was received on 13 Jan 2016, accepted on 13 Feb 2016 and first published on 15 Feb 2016


Article type: Research Article
DOI: 10.1039/C6QO00014B
Citation: Org. Chem. Front., 2016,3, 462-465
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    Primary alkyl bis-catecholato silicates in dual photoredox/nickel catalysis: aryl- and heteroaryl-alkyl cross coupling reactions

    C. Lévêque, L. Chenneberg, V. Corcé, J. Goddard, C. Ollivier and L. Fensterbank, Org. Chem. Front., 2016, 3, 462
    DOI: 10.1039/C6QO00014B

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