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Issue 12, 2016
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Phototriggered supramolecular polymerization of a [c2]daisy chain rotaxane

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Abstract

A new strategy for phototriggered supramolecular polymerization of the [c2]daisy chain is demonstrated. A daisy chain rotaxane containing two coumarin protected 2-ureido-4-pyrimidinone (Upy) terminals at two ends was designed, whose supramolecular polymerization can be initiated by light irradiation that can remove the photocleavable protecting coumarin groups and uncage the two terminal Upy functional units.

Graphical abstract: Phototriggered supramolecular polymerization of a [c2]daisy chain rotaxane

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Publication details

The article was received on 18 Feb 2016, accepted on 24 Feb 2016 and first published on 25 Feb 2016


Article type: Communication
DOI: 10.1039/C6PY00309E
Citation: Polym. Chem., 2016,7, 2166-2170
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    Phototriggered supramolecular polymerization of a [c2]daisy chain rotaxane

    X. Fu, R. Gu, Q. Zhang, S. Rao, X. Zheng, D. Qu and H. Tian, Polym. Chem., 2016, 7, 2166
    DOI: 10.1039/C6PY00309E

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